Condensation of Salts of Saturated Carboxylic Acids with Ethylene in the Presence of Alkaline Catalysts

L Schmerling, WG Toekelt

Index: Schmerling,L.; Toekelt,W.G. Journal of the American Chemical Society, 1962 , vol. 84, p. 3694 - 3697

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Abstract

Ethylation occurs when a dry mixture of a salt of a saturated carboxylic acid which contains at least one hydrogen atom attached to the a-carbon atom and an alkali metal catalyst is heated at 150-250 under ethylene pressure. Thus, the reaction of potassium acetate in the presence of sodamide yields a mixture of potassium di-and triethylacetate. Similarly, ethylation occurs at the a-carbon atom of sodium propionate, sodium isobutyrate, sodium ...