New Direct 11B NMR-Based Analysis of Organoboranes through Their Potassium Borohydrides

…, G Cruz, CR Cabrera, JA Soderquist

Index: Soderquist, John A.; Justo De Pomar, Jorge C. Tetrahedron Letters, 2000 , vol. 41, # 19 p. 3537 - 3539

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Citation Number: 10

Abstract

Representative organoborane mixtures were quantitatively converted to their borohydrides through their reaction with activated KH (KH*), permitting their detailed analysis by 11B NMR. Through the treatment of commercial KH with a THF solution of lithium aluminum