The Journal of Physical Chemistry

Self-termination and electronic spectra of substituted benzyl radicals in solution

RFC Claridge, H Fischer

Index: Claridge, Rodney F. C.; Fischer, Hanns Journal of Physical Chemistry, 1983 , vol. 87, # 11 p. 1960 - 1967

Full Text: HTML

Citation Number: 84

Abstract

Several substituted benzyl radicals have been generated in liquid cyclohexane by the photolysis of symmetrically substituted dibenzyl ketones. The rate constants for self- termination to substituted bibenzyls, and absorption spectra of the transient radicals, have been measured by optical modulation spectroscopy. The termination rates are generally well described by the von Smoluchowski equation with a spin factor of Deviations are ...

Kinetics of the reaction of the TEMPO radical with alkylaren...

[Opeida; Matvienko; Bakurova; Voloshkin Russian Chemical Bulletin, 2003 , vol. 52, # 4 p. 900 - 904]

The mechanism of formation of m-xylylene type biradicals pro...

[Haider; Migirdicyan; Platz; Soundararajan; Despres Journal of the American Chemical Society, 1990 , vol. 112, # 2 p. 733 - 738]

Absolute rate constants for the reaction of triethylsilyl ra...

[Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. Journal of Organic Chemistry, 1987 , vol. 52, # 5 p. 938 - 940]

Kinetic study of the phthalimide N-oxyl radical in acetic ac...

[Koshino, Nobuyoshi; Saha, Basudeb; Espenson, James H. Journal of Organic Chemistry, 2003 , vol. 68, # 24 p. 9364 - 9370]

Carbon-carbon and carbon-hydrogen bond splits of laser-excit...

[Brand, U.; Hippler, H.; Lindemann, L.; Troe, J. Journal of Physical Chemistry, 1990 , vol. 94, # 16 p. 6305 - 6316]