… Derivatives Functionalised with Tetrathiafulvalene (TTF) Units: X??Ray Crystal Structures of Two Related ttf Cyclophanes and Two Bis (1, 3??Dithiole??2??Thione) …

…, MR Bryce, AS Batsanov, JAK Howard

Index: Wang, Changsheng; Bryce, Martin R.; Batsanov, Andrei S.; Howard, Judith A. K. Chemistry - A European Journal, 1997 , vol. 3, # 10 p. 1679 - 1690

Full Text: HTML

Citation Number: 57

Abstract

Abstract The pyrazinoporphyrazine system 13 (metal-free, zinc and copper derivatives) has been synthesised by tetramerisation of 2, 3-dicyanopyrazine monomer unit 10. The structure of 13a-c has been established by 1 H NMR spectroscopy, UV/Vis spectrophotometry, MALDI- TOF mass spectrometry, cyclic voltammetry and differential pulse voltammetry. The electrochemical redox behaviour of 13a-c is strongly solvent dependent. The expected ...