Journal of the American Chemical Society

A new class of potential photoaffinity labels.. alpha.-Diazophosphonic acids: synthesis and stability

PA Bartlett, KP Long

Index: Bartlett,P.A.; Long,K.P. Journal of the American Chemical Society, 1977 , vol. 99, p. 1267 - 1268

Full Text: HTML

Citation Number: 16

Abstract

We are interested in a-diazophosphonic acids (3) as possible photoaffinity labeling reagents which may surmount these limitations. Our intention is that they may mimic the analogous phosphates (4) and make available a wide range of potential labeling reagents. In this communication we describe the synthesis and characterization of three diazophosphonic acids: the diethylsulfamoyl, diisopropylphosphono, and dimethylcarbamoyl derivatives of ...