Organic Magnetic Resonance

1H NMR studies of solvent and substituent effects on strong intramolecular hydrogen bonds

B Brzezinski, M Szafran

Index: Brzezinski, Bogumil; Szafran, Miroslaw Organic Magnetic Resonance, 1981 , vol. 15, # 1 p. 78 - 82

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Citation Number: 12

Abstract

Abstract Chemical shifts of H-bonded protons in tetrabutylammonium hydrogen maleate and 14-substituted picolinic acid N-oxides have been measured in a number of dry solvents, of different activity, in order to distinguish between symmetrical single minimum and asymmetrical hydrogen bonds. In tetrabutylammonium hydrogen maleate the resonance was observed at 20.70 ppm and its was independent of the nature of the solvent used. ...