Regio-and stereoselective. gamma. substitution of allylic alcohols with alkyllithium compounds by using N, N-methylphenylaminotributylphosphonium iodide. Anti …

Y Tanigawa, H Ohta, A Sonoda…

Index: Tanigawa,Y. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 4610 - 4612

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Citation Number: 40

Abstract

6a showed that these compounds exist in the conformations shown in Figure 1. The stereochemistry of epoxides was deduced from the expected exclusive or preferential (2-10 opening by analogy to previous results in the N-methyl series (3e, 4e) by Onda et and in the N-methyloctahydroisoquinoline series by Grob and WohLg