Journal of Organometallic Chemistry

Organoboranes: XIX. The preparation and some unusual chemistry of b-allyl derivatives of 9-borabicyclo [3.3. 1] nonane

GW Kramer, HC Brown

Index: Kramer,G.W.; Brown,H.C. Journal of Organometallic Chemistry, 1977 , vol. 132, p. 9 - 27

Full Text: HTML

Citation Number: 94

Abstract

Abstract Several B-allyl derivatives of 9-borabicyclo [3.3. 1] nonane (9-BBN) were prepared either by the allylation of B-methoxy-9-BBN with allylic aluminum re-agents or by the monohydroboration of certain dienes and allenes with 9-BBN. The 1 H NMR spectra of these derivatives were examined at various temperatures, revealing the presence of either permanent allylic rearrangements or cistrans isomerizations about the allylic double bond. ...