Oxidation and photochemical reactions of 3??phenyl??2H??1, 4??benzoxazines

P Battistoni, P Bruni, G Fava…

Index: Battistoni, P.; Bruni, P.; Fava, G.; Tosi, G. Journal of Heterocyclic Chemistry, 1983 , vol. 20, p. 451 - 455

Full Text: HTML

Citation Number: 9

Abstract

Abstract 3-Phenyl-2H-1, 4-benzoxazines 4-oxides are light sensitive compounds, irradiation leads to 3-phenyl-2H-1, 4-benoxazines and to their 3-oxidized derivatives, whenever possible. Intermediate oxaziridines are formed during the photolysis and transformed into stable nitroxide radicals. The structure of these radicals was confirmed through peracid oxidation of 3-phenyl-2H-1, 4-benzoxazines and 3-phenyl-3, 4-dihydro-2H-1, 4- ...