Molecules

Synthesis and photochemistry of 1-iodocyclohexene: influence of ultrasound on ionic vs. radical behaviour

M Blaskovicova, A Gaplovsky, J Blasko

Index: Blaskovicova, Marika; Gaplovsky, Anton; Blasko, Jaroslav Molecules, 2007 , vol. 12, # 2 p. 188 - 193

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Citation Number: 11

Abstract

Abstract: Simultaneous application of UV light and ultrasonic irradiation to a reaction mixture containing 1-iodocyclohexene is reported. The irradiation of 1-iodocyclohexene in methanol was carried out with or without addition of zinc. The effect of ultrasound or mechanical stirring on this solid-liquid system was also compared. The irradiation of 1-iodocyclohexene in methanol in the presence of zinc increases the yield of the nucleophilic trapping product ...