Journal of Molecular Structure

Formation of (NHN 1)+ hydrogen bonded cations in acetonitrile

Z Pawlak, G Urbańczyk

Index: Pawlak, Zenon; Urbanczyk, Gizela Journal of Molecular Structure, 1988 , vol. 177, p. 401 - 406

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Citation Number: 11

Abstract

Abstract The formation constants of the complexes formed between seven protonated N- bases and imidazole (Im) and imidazolium cation with twelve N-bases and the acidic dissociation K AN a (BH+) have been determined in acetonitrile AN. There exists a correlation between the pK AN a (acceptor)− pK AN a (donor) that form the heteroconjugated complexes. The experimental formation constants of the complexes,( ...