Catalytic Asymmetric Henry Reaction of Nitroalkanes and Aldehydes Catalyzed by a Chiral N, N′-Dioxide/Cu (I) Complex

H Mei, X Xiao, X Zhao, B Fang, X Liu…

Index: Elmaaty, Tarek Abou; Castle, Lyle W. Molecules, 2005 , vol. 10, # 12 p. 1458 - 1461

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Citation Number: 7

Abstract

... Volume: Page: ... diisopropylphenyl group, trace amount of product 2a was detected (Table 1, entry 7), while alkyl cyclohexyl subunit could promote the reaction in 65/60% ee and 69/31 anti/syn albeit with 17% yield ... 6, [Cu(CH 3 CN) 4 ]PF 6, L-PicP, 10, 58/42, 11/–12. ...