Palladium??Catalyzed Allylic Fluorination

…, M Tredwell, E Benedetto, M Huiban…

Index: Hollingworth, Charlotte; Hazari, Amaruka; Hopkinson, Matthew N.; Tredwell, Matthew; Benedetto, Elena; Huiban, Mickael; Gee, Antony D.; Brown, John M.; Gouverneur, Veronique Angewandte Chemie - International Edition, 2011 , vol. 50, # 11 p. 2613 - 2617

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Citation Number: 102

Abstract

Transition metal catalyzed allylic substitution is a powerful method for carbon–carbon and carbon–heteroatom bond formation and plays a pivotal role in modern organic synthesis.[1] These reactions encompass a wide variety of heteroatoms (N, O, S, Si, P) as nucleophiles. A transition metal catalyzed allylic fluorination would unveil new synthetic approaches towards highly valuable fluorinated compounds such as fine pharmaceuticals or 18F-labeled ...