Polyhedron

Synthesis and characterization of triphenyltin esters of heteroaromatic carboxylic acids and the crystal structure of [Ph 3 SnO 2 CC 5 H 4 N· 0.5 H 2 O]∞

HD Yin, CH Wang, QJ Xing

Index: Yin, Han-Dong; Wang, Chuan-Hua; Xing, Qiu-Ju Polyhedron, 2004 , vol. 23, # 10 p. 1805 - 1810

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Citation Number: 34

Abstract

The reaction of triphenyltin hydroxide with 2-furanyl, 2-furanvingl, 2-(5-terbutyl) furanyl, 2-(5- benzoyl) furanyl, 2-pyridinyl, 4-pyridinyl, 3-indolyl, 3-indolmethyl, 3-indolethyl and 3- indolpropyl carboxylates in 1: 1 stoichiometry yields triphenyltin esters of heteroaromatic carboxylic acids Ph3SnO2CR. All compounds are characterized by elemental analysis, IR and 1H NMR. The crystal structure of the triphenyltin ester of 4-pyridinyl carboxylic acid (6) ...