Solid-state reaction mechanisms in monomer-dimer interconversions of p-bromonitrosobenzene. Single-crystal-to-single-crystal photodissociation and formation of …

I Halasz, E Mestrovic, H Cicak, Z Mihalic…

Index: Halasz, Ivan; Mestrovic, Ernest; Cicak, Helena; Mihalic, Zlatko; Vancik, Hrvoj Journal of Organic Chemistry, 2005 , vol. 70, # 21 p. 8461 - 8467

Full Text: HTML

Citation Number: 26

Abstract

Thermal and photochemical reactions and the phase transition mechanisms of solid-state monomer-dimer interconversions of p-bromonitrosobenzene were studied on the basis of kinetics data and single-crystal-to-single-crystal transformations. From the crystal structure and packing of p-bromobenzeneazodioxide and the previously determined structure of the freshly sublimed monomer, we have explained both consecutive steps in thermal ...