Heteroatom Chemistry

N??(2??hydroxyaryl) benzamide synthesis from 2??nitroaryl benzoates via an indium??mediated reduction??migration reaction

H Lee, M Kim, YM Jun, BH Kim…

Index: Lee, Hyejeong; Kim, Minki; Jun, Young Moo; Kim, Byeong Hyo; Lee, Byung Min Heteroatom Chemistry, 2011 , vol. 22, # 2 p. 158 - 167

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Abstract

Abstract A one-pot reduction-triggered N-(2-hydroxyaryl) benzamide synthesis from 2- nitroaryl benzoate substrates was investigated. In the presence of indium/AcOH in THF/H 2 O, 2-nitroaryl benzoates produced reasonable yields of the benzo group migrated N-(2- hydroxyaryl) benzamides at room temperature within 1 h.© 2011 Wiley Periodicals, Inc. Heteroatom Chem 22: 158–167, 2011; View this article online at wileyonlinelibrary. com. ...