… alcohol-formation of a reagent for the facile introduction of a stabilizing bidentate ligand in compounds of hypervalent sulfur (10-S-4), phosphorus (10-P-5), silicon (10- …

…, RS Michalak, GD Figuly, WH Stevenson…

Index: Perozzi, Edmund F.; Michalak, Ronald S.; Figuli, Garret D.; Stevenson III, William H.; Dess, Daniel B.; et al. Journal of Organic Chemistry, 1981 , vol. 46, # 6 p. 1049 - 1053

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Citation Number: 113

Abstract

The reaction of 1, 1, 1, 3, 3, 3-hexafluoro-2-phenyl-2-propanol (RFOH) with either sec- butyllithium or n-butyl-lithium/N, N, IV, IV-tetramethylethylenediamine (TMEDA) provides 3, a reagent for the facile introduction of a bidentate ligand which is particularly effective in stabilizing the higher coordination states of nonmetallic elements. This reagent is used to prepare a series of spiro compounds in which two of these ligands are attached to ...