Recyclization of 1, 3, 4-Oxadiazoles and Bis-1, 3, 4-oxadiazoles into 1, 2, 4-Triazole Derivatives. Synthesis of 5-Unsubstituted 1, 2, 4-Triazoles

…, AV Knishevitsky, GF Raenko, TM Pekhtereva…

Index: Korotkikh; Kiselev; Knishevitsky; Raenko; Pekhtereva; Shvaika Chemistry of Heterocyclic Compounds, 2005 , vol. 41, # 7 p. 866 - 871

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Citation Number: 15

Abstract

Abstract Efficient methods have been developed for obtaining precursors of stable carbenes, viz. 5-unsubstituted 3, 4-diaryl-1, 2, 4-triazoles and 3, 3′-or 4, 4′-bridge linked bis-1, 2, 4- triazoles, by the recyclization of 5-unsubstituted 1, 3, 4-oxadiazoles or p-phenylenebis-1, 3, 4-oxadiazole with anilines or aromatic diamines in the presence of trifluoroacetic acid or with aniline hydrochlorides in pyridine.