Hydrolysis kinetics and mechanism of acyl-1, 3-diphenyltriazenes

O Pytela, M Večeřa, P Vetešník

Index: Pytela; Vecera; Vetesnik Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 4 p. 1269 - 1278

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Citation Number: 4

Abstract

Abstract The hydrolysis rate constants of 3-(N-methylcarbamoyl)-1, 3-diphenyltriazene (I), 3- (N-phenylcarbamoyl)-1, 3-diphenyltriazene (II) and 3-acetyl-1, 3-diphenyltriazene (III) have been determined in aqueous media within pH 0 to 14, H o to 3 and H-to 15. The hydrolysis at pH< 2 and pH> 11 show specific acid and base catalysis, respectively, whereas within pH 2 to 11 non-catalyzed hydrolysis takes place. Activation parameters of the non-catalyzed ...