Oxidation of thioketenes by singlet oxygen

VJ Rao, V Ramamurthy, E Schaumann…

Index: Rao, V. Jayathirtha; Ramamurthy, V.; Schaumann, E.; Nimmesgern, H. Journal of Organic Chemistry, 1984 , vol. 49, # 4 p. 615 - 621

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Citation Number: 8

Abstract

Results Singlet oxygen generated by dye sensitization (rose bengal, eosin, crystal violet, rhodamin B, and methylene blue) readily reacted with thioketenes 1 and 2 to give products shown in Schemes I and 11. Oxidation of 1 in methylene chloride, chloroform, and carbon tetrachloride

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Detail

~36%

~40%

~25%

Detail

~30%

~24%

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Oxidations of thio ketones by singlet and triplet oxygen

[Rao, V. Jayathirtha; Muthuramu, K.; Ramamurthy, V. Journal of Organic Chemistry, 1982 , vol. 47, # 1 p. 127 - 131]

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