MOLYBDENUM PENTACHLORIDE (MoC15) CATALYZES EFFICIENT DITHIOACETALIZATION OF CARBONYL COMPOUNDS AND TRANSDITHIOACETALIZATION …

H Firouzabadi, B Karimi

Index: Firouzabadi; Karimi Phosphorus, Sulfur and Silicon and Related Elements, 2001 , vol. 175, p. 207 - 216

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Citation Number: 7

Abstract

Abstract Dithioacetalization of carbonyl compounds was performed efficiently in CH2Cl2 at room temperature in the presence of MoCl5. Highly selective transdithioacetalization of acetals was also catalyzed efficiently by this catalyst. MoCl5 performed non-hydrolytic deprotection of dithioacetals in the presence of dry DMSO.

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