Small and Medium Rings, 74. Syntheses and Photoelectron Spectra of 7??Azanorbornadiene and Related Compounds An Analysis with Fragment Orbitals

HJ Altenbach, HD Martin, B Mayer, M Müller…

Index: Altenbach, Hans-Josef; Constant, Dieter; Martin, Hans-Dieter; Mayer, Bernhard; Mueller, Monika; Vogel, Emanuel Chemische Berichte, 1991 , vol. 124, # 4 p. 791 - 801

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Citation Number: 35

Abstract

Abstract The He (I) photoelectron spectra (PE) of 7-azanorbornane (5), 7-azanorbornene (6), and 7-azanorbornadiene (7) as well as of related urethanes have been recorded. The syntheses of these bicyclic compounds are described in detail. A most convenient analysis of the PE spectroscopic results is based on the procedure of Heilbronner-Schmelzer on an ab initio STO-3G level. This method allows to construct fragment orbitals elucidating the ...