A new method for the activation of ethyl benzenesulfenate in electrophilic addition reactions

…, AY Gavrilova, OA Mukhina, OB Bondarenko…

Index: Zyk; Gavrilova, A. Yu.; Mukhina; Bondarenko; Zefirov Russian Chemical Bulletin, 2008 , vol. 57, # 12 p. 2572 - 2578

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Citation Number: 4

Abstract

Abstract Reactions of unsaturated compounds with the PhSOEt-SOHal 2 and PhSOEt-Me 3 SiHal systems (Hal= Cl or Br) were proposed as a new route to haloalkyl phenyl sulfides. With acyclic and mono-and bicyclic alkenes and dienes as examples, the regio-and stereoselectivity of the reactions were studied.