Rates of alkaline hydrolysis of N-alkyl acetates and their ω-tert-butyl, ω-trimethylsilyl and ω-trimethylgermyl derivatives

J Pola, V Chvalovský

Index: Pola,J.; Chvalovsky,V. Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, p. 2247 - 2252

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Citation Number: 6

Abstract

Rates of alkaline hydrolysis of n-alkyl acetates CH3 (CH2) n0COCH3 (n= 2-8, 11), their tert- butyl derivatives (CH 3) 3 C (CH2) nOCOCH3(n= 1-4), trimethylsilyl derivatives (CH3) 3Si (CH2) n. OCOCH 3 (n= 1-6), and trimethylgermyl derivatives (CH3hGe (CH2) nOCOCH3 (n= 1-4) were measured. Kinetic data were interpreted in terms of predominant steric effect of the alkoxy group.