Journal of organometallic chemistry

Catalysis of hydrosilylation: XX. Unusual reaction of vinyltriethoxysilane with triethoxysilane catalyzed by nickel acetylacetonate

B Marciniec, H Maciejewski, J Mirecki

Index: Marciniec, Bogdan; Maciejewski, Hieronim; Mirecki, Janusz Journal of Organometallic Chemistry, 1991 , vol. 418, # 1 p. 61 - 67

Full Text: HTML

Citation Number: 19

Abstract

Abstract Nickel acetylacetonate is shown to be a catalyst of an unusual reaction of vinyltriethoxysilane with triethoxysilane involving formation of bis (silyl) ethene and bis (silyl) butanes as the main products accompanied by others of direct and dehydrogenative hydrosilylation, bi (silyl) ethane and ethylsilane as well as products of redistribution of triethoxysilane and formation of oligomers. The latter reaction is a consequence of ...