The Chemistry of Sultones. II. Alkylations of Organometallic and Related Compounds by Sultones1

WE Truce, FD Hoerger

Index: Truce; Hoerger Journal of the American Chemical Society, 1955 , vol. 77, p. 2496,2498

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Citation Number: 5

Abstract

Sodium ethoxide, sodium benzenesulfinate, phenJ. lethJ-nylsotiium, n-but> llithium and the sodium derivatives of diethyl malonate, ethyl acetoacetate and dibenzol lmethane are alkyldted readil! by 4-hydroxJ-1-butanesulfonic acid sultone. The reaction of 4-hydroxy-1- butanesulfonic acid sultone with phenylmagnesium bromide produces both magnesium 4- phenyl-lbutanesulfonate and magnesium 4-bromo-1-butanesulfonate. The reaction of 2-o- ...