Tetrahedron

Self-assembly of supramolecular oligo-phenylene-ethynylene wires consisting of double Hamilton receptor modified OPE rods and a tetraphenylporphyrin cyanurate

F Wessendorf, A Hirsch

Index: Wessendorf, Florian; Hirsch, Andreas Tetrahedron, 2008 , vol. 64, # 50 p. 11480 - 11489

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Citation Number: 21

Abstract

The syntheses and characterizations of new oligo-phenylene-ethynylene (OPE) bridged bis- Hamilton receptors 8–9 and their linear H-bonding behaviour with a new cyanuric acid modified tetraphenylporphyrin (TPP) 13 are reported. The resulting rigid complexes consisting of an oligo-phenylene-acetylene wire and two terminating TPPs were characterized by 1H NMR, UV/vis and fluorescence spectroscopies. The 1: 2 compositions ...