Reactions of t-Alkyl Hypochlorites with Trisubstituted Phosphines and Phosphites

DB Denney, RR DiLeone

Index: Denney,D.B.; DiLeone,R.R. Journal of the American Chemical Society, 1962 , vol. 84, p. 4737 - 4743

Full Text: HTML

Citation Number: 33

Abstract

(8) Rindly provided by Hotfman-La Roche Co.(9) The nature of these impurities was not further investigated. Recent work by FD Greene, ML Savitz. HH Lau, FD Osterholtz and WN Smith, 1. Am. Chcm. SOC., 83, 2196 (1961), and C. Walling and A. Padwa, ibid., 83, 2208 (1961), on the decompositioc of t-alkyl hypochlorites provides an understanding of what they might be. These authors have shown that chloroalcohols are often formed by the free ...