Tetrahedron letters

The interconversion of primary alkyl halides

I Bidd, MC Whiting

Index: Bidd, I.; Whiting, M. C. Tetrahedron Letters, 1984 , vol. 25, # 51 p. 5949 - 5950

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Citation Number: 8

Abstract

Summary: Using tetra-alkylammonium halides dissolved in alkyl halides as reagents a variety of halogen exchange reactions can be carried out conveniently in high yield. In particular, it becomes practicable to use -CH2Cl as a protected equivalent of -CH2Br. ... In work on the synthesis of aliphatic compounds of very long chain-length 192 two anti- thetical problems arose. The first was the undesired conversion of primary bromides to chlorides; as these are some 250 ...