Tetrahedron letters

Enzymatic alcoholysis of alkoxymethyl alkanoates: a possible approach for the kinetic resolution of tertiary alcohols

MCR Franssen, ELV Goetheer, H Jongejan…

Index: Franssen, Maurice C.R.; Goetheer, Earl L.V.; Jongejan, Hugo; De Groot, Aede Tetrahedron Letters, 1998 , vol. 39, # 45 p. 8345 - 8348

Full Text: HTML

Citation Number: 18

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The pivaloyloxymethyl and butanoyloxymethyl derivatives of tert-butanol and linalool (1, 4) are readily accepted by hydrolases. Linalool derivative 4b is alcoholysed stereoselectively by Candida rugosa lipase (E=9.7). ... Alkoxymethyl alkanoates obtained from tertiary alcohols (4) ...

 Related Synthetic Route
Chloromethyl pivalate Structure

18997-19-8

Chloromethyl pi...

~%

Propanoic acid, 2,2-dimethyl-, butyl ester Structure

5129-37-3

Propanoic acid,...

N/A Structure

216861-19-7

N/A

~%

(-)-Linalool Structure

126-91-0

(-)-Linalool

n-Butyl butanoate Structure

109-21-7

n-Butyl butanoate

dextro-linalool Structure

126-90-9

dextro-linalool

N/A Structure

216861-19-7

N/A

Butanol Structure

71-36-3

Butanol

~%

(-)-Linalool Structure

126-91-0

(-)-Linalool

n-Butyl butanoate Structure

109-21-7

n-Butyl butanoate

Detail

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