Chemische Berichte

Übergangsmetall??katalysierte Reaktionen von ungesättigten α??Diazo?螃窿?(trimethylsilyl) essigestern mit Carbonylverbindungen

M Alt, G Maas

Index: Alt, Mechthild; Maas, Gerhard Chemische Berichte, 1994 , vol. 127, # 8 p. 1537 - 1542

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Citation Number: 20

Abstract

Some reactions of unsaturated a-diazo-a-(trimethylsily1) acetates with aldehydes or acetone under the catalytic action of rhodium (I1) perfluorobutyrate or copper (1) triflate have been investigated. Thus, the allylic ester 6a affords 1, 3-dioxolan-4-ones 8 under Rh (I1) catalysis;