Angewandte Chemie International Edition

A Practical and Mild Method for the Highly Selective Conversion of Terminal Alkenes into Aldehydes through Epoxidation–Isomerization with Ruthenium (IV)– …

J Chen, CM Che

Index: Chen, Jian; Che, Chi-Ming Angewandte Chemie - International Edition, 2004 , vol. 43, # 37 p. 4950 - 4954

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Citation Number: 116

Abstract

type oxidation” of terminal alkenes [4, 5] reported herein apparently proceeds by a different mechanism to those proposed for the palladium-or palladium/copper-catalyzed reactions.[2] We also report herein a direct one-pot diazoacetate olefination of aldehyde substrates generated in situ by this ruthenium–porphyrin-catalyzed oxidation of alkenes. When a solution of 1-phenyl-1, 3-butadiene (3), Cl2pyNO (1.03 equiv), and catalyst 1 (0.5 mol%) in ...

~98%

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