Biphenyl??Based Diaminophosphine Oxides as Air??Stable Preligands for the Nickel??Catalyzed Kumada–Tamao–Corriu Coupling of Deactivated Aryl Chlorides, …

…, YJ Li, YQ Ma, LL Qiu, JX Fang

Index: Jin, Zhong; Li, Yan-Jing; Ma, Yong-Qiang; Qiu, Ling-Ling; Fang, Jian-Xin Chemistry - A European Journal, 2012 , vol. 18, # 2 p. 446 - 450

Full Text: HTML

Citation Number: 27

Abstract

Transition-metal-catalyzed cross-coupling reactions [1] of aryl halides or pseudo-halides with organometallic reagents, such as Grignard reagents, organozinc compounds, boronic acids, organostannanes, and organosiloxanes, are powerful tools for the synthesis of the biaryl motif, which is prevalent in natural products, pharmaceuticals, chiral ligands, liquid crystals, and macromolecular polymers. Over the last decade, transition-metal-catalyzed ...