The Journal of Organic Chemistry

Mild halogenation of stabilized ester enolates by cupric halides

X Shi, L Dai

Index: Shi, Xiao-Xin; Dai, Li Xin Journal of Organic Chemistry, 1993 , vol. 58, # 17 p. 4596 - 4598

Full Text: HTML

Citation Number: 39

Abstract

The reactions of various stabilized ester enolates of 2-keto, 2-(alkoxycarbonyl), 2- phosphoryl, and 2-(benzenesulfonyl) esters with cupric chloride or cupric bromide have been examined. The reactions lead to 2-halo esters in good to excellent yields under mild