Chemistry of Isocyanic Acid. I. Reactions of Isocyanic Acid with Carbonyl Compounds

FW Hoover, HB Stevenson…

Index: Hoover,F.W. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 1825 - 1830

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Citation Number: 29

Abstract

number of a-hydroxy isocyanates, a new class of compounds, have been synthesized from isocyanic acid and carbonyl compounds such as formaldehyde, chloral, s- dichlorotetrafluoroacetone, trifluoroacetaldehyde, and perfluorocyclobutanone. These novel isocyanates undergo most of the normal isocyanate reactions. They can be converted readily to 1, 3, 5-oxadiazine-2, 4-diones and to a-chloro isocyanates, an unusually ...