The Reaction of Diazocyclopentadienyl Compounds with Cyclomanganated Arenes as a Route to Ligand??Appended Cymantrenes

…, N Kyritsakas??Gruber, A de Cian…

Index: Djukic, Jean-Pierre; Michon, Christophe; Heiser, Dirk; Kyritsakas-Gruber, Nathalie; De Cian, Andre; Doetz, Karl Heinz; Pfeffer, Michel European Journal of Inorganic Chemistry, 2004 , # 10 p. 2107 - 2122

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Citation Number: 12

Abstract

Abstract The thermolysis of various cyclomanganated arenes in the presence of 5- diazocyclopentadiene, 7-diazoindene or 9-diazofluorene afforded the corresponding arenes tethered with cymantrenyl, benzocymantrenyl or dibenzocymantrenyl groups in fair to good yields. This reaction implies a multi-facetted mechanism that consists of three steps: the insertion of an alkylidene moiety into a C− Mn bond, a C Ar− C bond formation and ...