Palladium catalysed direct allylation of pronucleophiles with allylstannanes

Y Yamamoto, N Fujiwara

Index: Yamamoto, Yoshinori; Fujiwara, Naoya Journal of the Chemical Society, Chemical Communications, 1995 , # 19 p. 2013 - 2014

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Citation Number: 2

Abstract

The reaction of pronucleophiles 1 with allyltributylstannanes in the presence of catalytic amounts of Pd2 (dba) 3· CHCl3 (4 mol%) and 1, 2-bis (diphenylphosphino) ethane (dppe)(10 mol%) at room temperature gives the corresponding allylation products in good to high yields.

~40%

~50%

~73%

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