Synthesis and Thermolysis of Cycloalkenyl Azides and Iminophosphoranes Aldehydes: A New Pathway to Bisannelated Pyridines

B Tabyaoui, T Aubert, M Farnier…

Index: Tabyaoui, B.; Aubert, T.; Farnier, M.; Guilard, R. Synthetic Communications, 1988 , vol. 18, # 13 p. 1475 - 1482

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Citation Number: 10

Abstract

Abstract Nucleophilic substitution on vinyl halides usually occurs when these compounds possess an electron withdrawing group at the D position as well as a good leaving group at the Q position Thus D-chlorovinyl ketones are suitable starting materials for the synthesis of D-azidovinyl ketones' Nesmeyanov and Rybuiskaya2 found that this substitution proceeds with the retention of configuration regarding the C= C bond Consequently, trans-β- ...