Journal of Organometallic Chemistry

Unprecedented effects of the trimethylsilyl group on the reactivity of 3C-silylated silacyclopentenes and their derivatives

R Boukherroub, G Manuel

Index: Boukherroub, Rabah; Manuel, Georges Journal of Organometallic Chemistry, 2000 , vol. 604, # 2 p. 141 - 149

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Citation Number: 4

Abstract

We have synthesised new 3C-silylated silacyclopentenes from the corresponding 3- trimethylsilyl-1, 1-dichloro-1-silacyclopent-3-enes. The presence of two metal centres M (M= Si) in α and β-positions confers an original structure for these new heterocycles. The chemical behaviour of such compounds and their derivatives was studied and compared to the results obtained in the non-substituted silacyclopentane series.

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α-et β-silacyclopentanols

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