Reaction of arylglyoxals with electron??rich benzenes and π??excessive heterocycles. Facile synthesis of heteroaryl α??acyloins

SP Ivonin, AV Lapandin, AA Anishchenko…

Index: Ivonin, Sergey P.; Lapandin, Andrey V.; Anishchenko, Andrey A.; Shtamburg, Vasilii G. Synthetic Communications, 2004 , vol. 34, # 3 p. 451 - 461

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Citation Number: 20

Abstract

The reaction of arylglyoxals and their hydrates with electron??rich benzenes and π??excessive heterocycles, if conducted in the absence of catalysts, affords α??benzoins. ... The reaction of arylglyoxals and their hydrates with electron??rich benzenes and π??excessive heterocycles, if conducted in the absence of catalysts, affords α??benzoins. ... Arylglyoxals are soft electrophilic reagents able to react with aromatic and heterocyclic compounds. Such reactions ...