Titanocene dichloride complexes bonded to carbosilane dendrimers via a spacer of variable length–Molecular dynamics calculations and catalysis of allylic coupling …

T Strašák, F Jaroschik, M Malý, J Čermák, J Sýkora…

Index: Strasak, Tomas; Jaroschik, Florian; Maly, Marek; Cermak, Jan; Sykora, Jan; Fajgar, Radek; Karban, Jindrich; Harakat, Dominique Inorganica Chimica Acta, 2014 , vol. 409, # PART A p. 137 - 146

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Citation Number: 3

Abstract

Abstract Carbosilane metallodendrimers of the first generation Si {CH 2 CH 2 CH 2 SiMe 2 CH 2 CH 2 SiMe 2 (CH 2) n C 5 H 4 TiCl 2 C 5 H 5} 4 and Si {CH 2 CH 2 CH 2 SiMe [CH 2 CH 2 SiMe 2 (CH 2) n C 5 H 4 TiCl 2 C 5 H 5] 2} 4 (n= 1, 5) and of the second generation Si {CH 2 CH 2 CH 2 SiMe [CH 2 CH 2 CH 2 SiMe 2 CH 2 CH 2 SiMe 2 (CH 2) n C 5 H 4 TiCl 2 C 5 H 5] 2} 4 (n= 1, 5) and Si {CH 2 CH 2 CH 2 SiMe [CH 2 CH 2 CH 2 SiMe (CH 2 CH 2 ...