The molecular structure of 1-lithio-2-methoxybenzene in the solid state and in solution

…, J Boersma, L Brandsma, GPM van Mier…

Index: Harder, Sjoerd; Boersma, Jaap; Brandsma, Lambert; Mier, Guido P. M. van; Kanters, Jan A. Journal of Organometallic Chemistry, 1989 , vol. 364, p. 1 - 16

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Citation Number: 29

Abstract

Abstract The X-ray structure of 1-lithio-2-methoxybenzene (2-methoxyphenyllithium) has been determined at 298 K by single crystal X-ray techniques. The compound crystallizes in the triclinic system with spacegroup P 1. Cell dimensions: a 8.889 (2), b 11.710 (5), c 12.941 (3) Å, α 80.47 (3), β 84.22 (2), γ 82.37 (3). The structure has been refined toR (F)= 0.069 for 1300 unique observed reflections withI≥ 2.5 σ (I). Each unit-cell contains two ...