The synthesis of the chloro and dichloro derivatives of 2, 10-dihydroxydicyclohepta (b, d) furan-3, 9-diones.

T Kusaba, A Mori, H Takeshita

Index: Kusaba, Tomoyuki; Mori, Akira; Takeshita, Hitoshi Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 2 p. 515 - 520

Full Text: HTML

Citation Number: 6

Abstract

4, 8-Dichloro-and 5, 7-dichloro-2, 10-dihydroxydicyclohepta [b, d] furan-3, 9-diones were synthesized. Although the latter could be obtained by condensation of 4-chloro-p- tropoquinone and its hydroquinone, the former required the hydrolysis of condensate of 3- chloro-p-tropoquinone and 7-chloro-5-hydroxy-2-methoxytropone. This mixed condensation led to several unsymmetrically substituted derivatives in improved yields.