Tetrahedron

Selective mixed coupling of carboxylic acids (I).-Electrolysis, thermolysis and photolysis of unsymmetrical diacyl peroxides with acyclic and cyclic alkyl groups

M Feldhues, HJ Schafer

Index: Feldhues, Michael; Schaefer, Hans J. Tetrahedron, 1985 , vol. 41, # 19 p. 4195 - 4212

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Citation Number: 14

Abstract

14 Unsymmetrical diacyl peroxides (R1CO2-O2CR2 with R1: undecyl; R2: eg methyl, propyl, pentyl, nonyl, 2-methylpropyl, 2-propyl, 2-pentyl, cyclopropyl, cyclobutyl, cyclohexyl) are prepared in 85 to 92% yield. Square pulse electrolysis of dodecanoyl octanoyl peroxide (li)