Hydrolysis rate of functionalized fullerenes bearing alkoxysilanes: A comparative study

…, M Maggini, M Nogarole, G Scorrano

Index: Bianco, Alberto; Maggini, Michele; Nogarole, Marco; Scorrano, Gianfranco European Journal of Organic Chemistry, 2006 , # 13 p. 2934 - 2941

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Citation Number: 12

Abstract

Abstract Soluble fulleropyrrolidines bearing a trialkoxysilyl functionality (methoxy, ethoxy, butoxy, and isopropoxy) have been prepared and characterized. The hydrolysis rate constant for each fulleropyrrolidine was measured with 1 H NMR spectroscopy by following the disappearance of selected resonances of the fullerene substrate under the conditions (HCl/H 2 O/THF) used for the preparation of fullerene-doped sol–gel glasses. It has been ...