Copper (II) Complex with the Tridentate Ligand N, N??bis (2??ethyl??4??methyl??imidazol??5??ylmethyl) phenylethylamine (biaq). X??ray Crystal Structure and Biological …

…, G Mendoza??Díaz, M Pedraza??Reyes…

Index: Mendoza, Angeles; Mendoza-Diaz, Guillermo; Pedraza-Reyes, Mario; Bernes, Sylvain Zeitschrift fur Anorganische und Allgemeine Chemie, 2013 , vol. 639, # 8-9 p. 1455 - 1460

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Abstract

Abstract The ligand N, N-bis (2-ethyl-4-methyl-imidazol-5-ylmethyl)-1-phenylethylamine (biaq) was prepared by Mannich reaction of 2-ethyl-4-methyl-1H-imidazole,(R)-1- phenylethylamine and formaldehyde. It was characterized by FTIR and NMR spectroscopy. This ligand reacts with CuCl 2 to give a coordination compound with formula [Cu (biaq) Cl 2]. In this compound, biaq acts as a tridentate ligand with one tertiary amine and two azole ...