e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

The Journal of Organic Chemistry

A New Rearrangement Reaction1

MS NEWMAN, I UNGAR

Index: Newman,M.S.; Ungar,I. Journal of Organic Chemistry, 1962 , vol. 27, p. 1238 - 1240

Full Text: HTML

Citation Number: 2

Abstract

The yield of V from 111 is sensitive to the base used, time of heating, temperature, and solvent. Most of our studies involved the use of sodium carbonate since bases such as pyridine, collidine, and triethylamine did not bring about the rearrangement, while stronger bases, such as metallic hydroxides, afforded much resinous material. When ethylene glycol was used as solvent, the optimum temperature was in the 120-140O range, the optimum ...

Benzoyl chloride Structure

Benzoyl chloride

chlorophenylsulfone Structure

chlorophenylsulfone

monomethylhydrazine Structure

monomethylhydrazine

~%

Benzenesulfonic acid, 2-benzoyl-2-methylhydrazide Structure

Benzenesulfonic...

Benzoic acid,2-(phenylsulfonyl)hydrazide Structure

Benzoic acid,2-...

allyl bromide Structure

~%

N-(benzenesulfonyl)-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

Benzoic acid,2-(phenylsulfonyl)hydrazide Structure

Benzoic acid,2-...

~%

N-[3-(benzenesulfonyl)propylideneamino]-2,4-dinitro-aniline Structure

N-[3-(benzenesu...

N-(benzenesulfonyl)-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

~%

N-[3-(benzenesulfonyl)propylideneamino]-2,4-dinitro-aniline Structure

N-[3-(benzenesu...

N-[3-(benzenesulfonyl)propylideneamino]benzamide Structure

N-[3-(benzenesu...

2,4-Dinitrophenylhydrazine Structure

2,4-Dinitrophen...

~%

N-[3-(benzenesulfonyl)propylideneamino]-2,4-dinitro-aniline Structure

N-[3-(benzenesu...

Benzoyl chloride Structure

Benzoyl chloride

~%

N-(benzenesulfonyl)-N-methyl-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

chlorophenylsulfone Structure

chlorophenylsulfone

~%

N-(benzenesulfonyl)-N-methyl-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

Benzenesulfonic acid, 2-benzoyl-2-methylhydrazide Structure

Benzenesulfonic...

allyl bromide Structure

~%

N-(benzenesulfonyl)-N-methyl-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

N-(4-methylphenyl)sulfonyl-N-prop-2-enyl-benzohydrazide Structure

N-(4-methylphen...

~%

Benzoic acid,[3-[(4-methylphenyl)sulfonyl]propylidene]hydrazide (9CI) Structure

Benzoic acid,[3...

N-(4-methylphenyl)sulfonylbenzohydrazide Structure

N-(4-methylphen...

~%

Benzoic acid,[3-[(4-methylphenyl)sulfonyl]propylidene]hydrazide (9CI) Structure

Benzoic acid,[3...

Benzohydrazide Structure

~%

Benzoic acid,[3-[(4-methylphenyl)sulfonyl]propylidene]hydrazide (9CI) Structure

Benzoic acid,[3...

Tosyl chloride Structure

~%

Benzoic acid,[3-[(4-methylphenyl)sulfonyl]propylidene]hydrazide (9CI) Structure

Benzoic acid,[3...

N-(benzenesulfonyl)-N-prop-2-enyl-benzohydrazide Structure

N-(benzenesulfo...

~%

N-[3-(benzenesulfonyl)propylideneamino]benzamide Structure

N-[3-(benzenesu...

Benzoic acid,2-(phenylsulfonyl)hydrazide Structure

Benzoic acid,2-...

~%

N-[3-(benzenesulfonyl)propylideneamino]benzamide Structure

N-[3-(benzenesu...

Benzohydrazide Structure

Tosyl chloride Structure

~%

N-(4-methylphenyl)sulfonylbenzohydrazide Structure

N-(4-methylphen...

Benzohydrazide Structure

~%

N-(4-methylphenyl)sulfonyl-N-prop-2-enyl-benzohydrazide Structure

N-(4-methylphen...

Tosyl chloride Structure

~%

N-(4-methylphenyl)sulfonyl-N-prop-2-enyl-benzohydrazide Structure

N-(4-methylphen...

N-(4-methylphenyl)sulfonylbenzohydrazide Structure

N-(4-methylphen...

allyl bromide Structure

~%

N-(4-methylphenyl)sulfonyl-N-prop-2-enyl-benzohydrazide Structure

N-(4-methylphen...

Benzohydrazide Structure

acrolein Structure

~%

Benzoicacid, 2-(2-propen-1-ylidene)hydrazide Structure

Benzoicacid, 2-...