Chemische Berichte

Zur Kenntnis der thermischen Umlagerung des Bicyclo [1.1. 0] butan??Systems. Eine kinetische Studie des Übergangs von Tricyclo [4.1. 0.02, 7] heptanen in Bicyclo [ …

M Christl, R Stangl, H Jelinek??Fink

Index: Stangl, Roland; Jelinek-Fink, Hans; Christl, Manfred Chemische Berichte, 1992 , vol. 125, # 2 p. 479 - 484

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Citation Number: 5

Abstract

Tricyclo [4.1. 0.02~ f] heptane (?), its 1-(20) and 2-phenyl derivatives (22), tetracyclo [5.1. 0.02~ 4.03~ 5] octane (17), 1, 2, 3, 4-tetrahydro-1, 2, 3-methenonaphthalene (25) as well as its 1-(35), 2-(32), and 3-phenyl derivatives (27) have been thermolyzed in solution in the temperature range between 110 and 230 C. The activation parameters of these reactions have been determined. The parent hydrocarbon 7 is converted into bicyclo [3.2. 0] hept-6- ...