Tetrahedron letters

Lewis acid mediated reactions of 2-stannyl-3-silylpropene with acid chlorides. Formation of vinylsilanes via 1, 2-silyl migration and destannylation.

KT Kang, JC Lee, SU Jong

Index: Kang; Lee; U Tetrahedron Letters, 1992 , vol. 33, # 34 p. 4953 - 4956

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Citation Number: 11

Abstract

... 2; Kang, K. -T.; Kim, SS; Lee, JC; U, JS Tetrahedron Lett. in press. 3; JP Pilot, J. Deleris, R. Calas; J. Org. Chem., 44 (1979), p. 3397 and references therein. 4; Spectral data for the selected vinylsilanes are given below. 3b: 1 H-NMR (CDCl 3 ) δ 0.08 (s, 9H), 1.88 (d, 3H, J = 1.2 Hz), 2.14 (d, 3H, J = 1.2 Hz), 3.21 (s, 2H), 5.50–5.54 (m, 1H), 5.63–5.67 (m, 1H), 6.07–6.11 (m, 1H ...