Tetrahedron letters

Palladium (ii) catalyzed thiono-thiolo rearrangement of propargyl thionophosphates

Y Yamada, G Suzukamo, H Yoshioka, Y Tamaru…

Index: Yamada, Yoshimi; Suzukamo, Gohfu; Yoshioka, Hirosuke; Tamaru, Yoshinao; Yoshida, Zen-ichi Tetrahedron Letters, 1984 , vol. 25, # 33 p. 3599 - 3602

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Citation Number: 14

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Palladium(II) effectively catalyzes the [3,3]-sigmatropic type rearrangement of propargyl thionophosphates to provide allenyl thiolophosphates specifically. ... A mixture of S-1,,2-butadien-3-yl and S-2-butyn-1-yl diethyl phosphorothiolates (in a ratio of 23:77) was obtained by the Pd(O) ...